You could do this as an outside corner, with just a little piece of rail.
I did this with some baseboard right beside a closet (that I didn't want to put trim around), and it turned out well. (Taking this picture also reminds me, I never did quite finish cleaning this all up).
The hardest part of doing this is cutting the edge piece so you get a perfect corner.
- Cut the piece (usually there's a scarp piece around that will work). Go longer rather than shorter.
- Use wood glue or a construction adhesive (like No More Nails) and a clamp to attach it, with the edges meeting. Let it sit overnight to dry.
- Sand off any excess glue that came out.
- If needed, sand down the back side so it's flat (if you cut it a bit too long). A couple seconds on a belt sander is perfect.
That's really all there is to it. In your case, you may want to also sand down the front corner a bit so it's smoother, rather than sharp and likely to poke someone.
In the general sense, a physical border like tile cap or chair rail between two building materials is usually aesthetic, provided that the materials were installed properly. The one exception to this is in the case of a material with significant expansion potential with changes in climate (namely wood); in that case, a border can hide the necessary expansion joint. While that may apply here, the proper solution to allow for expansion is a bead of silicone caulk between the different materials.
Frankly, this job looks very poorly done, and I would question exactly how they got a flush surface. My guess is that they installed backer up to a certain point, tiled over the backer board (with or without an underlayment) and then installed gypsum drywall above that to create the flush surface (concrete backer + tile ~= one layer of drywall in thickness). The problem is that the grout of the last course (which is porous and not waterproof) is right up against drywall (or plaster, joint compound, or other porous non-waterproof building material). The end result will be that the grout will absorb water and wick it upwards to the drywall, which will absorb it and disintegrate. Generally speaking, two porous materials should never contact each other when moisture is a concern; the material that can handle moisture permeation (concrete, grout, earth) will wick it into the material that cannot (wood, drywall, plaster) and degrade it over time.
Anyway, what I would do in this case, if you wanted to try to save it, is remove the grout between the tile and drywall wherever it exists, and then install a T-border of some impervious substance as a barrier between the two materials, bedded in an adhesive caulk. The T-border will help prevent moisture transfer between tile and drywall, and provide a clean line between the two materials.
That's not an ideal solution, and honestly, if I were you and had the money to tear it all down and start over from the studs, it would give me the peace of mind that everything had been done properly. A couple of pictures give the impression that the previous homeowners didn't finish their reno, so there may be very little in it if you just started over. I also see inconsistencies in tile height, alignment, fit/finish, etc that tell me the installer didn't know or didn't care how to do it right, which means there could be serious underlying issues that could bite you. But, money's always an issue, and if you don't know how to DIY it properly and can't afford to hire the job out then I would tell you to try to make the best of what's there.
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Although this is sort of an arbitrary question, and might get flagged, I'll pen a few thoughts.
There are no real rules to chair rails, I've installed them from 28 to 38 inches. Traditionally, some feature, like a window sill or a side board dictates the height so the lines flow around the room. But I always say, "beauty is in the eyes of the beholder". If you decide to go higher than your sill, be sure to back cut the rail 3 or 4 degrees so it will fit snug to the window trim, no gaps.
Finishing at an outside corner is pretty straight forward. The rail should meet the edge of the outside corner perfectly with a 30 degree miter cut. I think cutting short of the corner makes it look unfinished, especially finishing with a straight cut at the inside corner. The end miter cut needs to be sanded really smooth so no cut off wood grain shows through your paint. I use a fixed rotatory sander for that job, but a delicate touch with a decent palm sander will work.
Just my humble opinion, hope your job looks great when your done. Good luck.