It doesn't sound like the #14 and #12 grounding wires being connected is the issue, to me.
EDIT:
NEC 250.148 (C) Metal Boxes. A connection shall be made between the
one or more equipment grounding conductors and a metal box by means of
a grounding screw that shall be used for no other purpose, equipment
listed for grounding, or a listed grounding device.
The OP uploaded a picture showing that the #12 is an independent circuit, in new 12/2 w/ground NM cable. So what you actually have is grounding via the BX armor, presuming that the BX tightly clamped in both this box and the service panel, and grounding through the #12 wire in the 12/2 circuit, and the two should be bonded together to the metal box.
The ground path through the BX is likely to have higher resistance than the ground path through that nice clean #12 copper. The metal box has to be grounded no matter what. I say leave all the grounds bonded together and to the box, and make sure the BX clamp is clean and tight at the junction box and back at the panel. If you're really concerned about the grounding through the BX sheath, try to run another lone ground wire back to the panel, or pull new NM cable to replace the BX.
Also, you would get a much tighter connection between the armored cable and the box using a better clamp than the one built-in to that old box, something like one of the following (that red plastic bushing protects the wires from sharp edges, so you never energize your grounding system accidentally):
END EDIT
All of the grounds in your house are ultimately bonded together, anyway, to zero the voltage differential all over your house (Neutrals are different! The neutrals are only bonded to the grounding bus in the main panel, nowhere else, and neutrals can only be shared by two circuits under specific conditions).
You wouldn't want a large circuit using a too-skinny conductor for grounding, though.
It sounds to me as if the original circuit is possibly BX armored cable, and the flexible conduit itself is the only grounding conductor going back from this junction box to the panel.
This not up to current code if the flexible metal conduit is the only ground path--there can be continuity problems through the flexible armor. BX was actually demarketed for a while, then came back as armored cable with a metal bonding strip that makes contact with the flexible conduit all along it's length to ensure a good ground path.
However; if you can somehow run a #12 bare or green-insulated wire back from that junction box to the panel (route it up through the attic?) and bond it to the grounding bus inside the panel, as well as to both the #12 and #14 wires, and the BX armor in the junction box by using the right metal clamps and bonding the wire to the metal box, you'd be perfectly fine.
Having said all that, I guess somebody could argue that some grounding through the BX armor is better than no grounding. But if you're in there messing around, you want to do it right and bring it up to code.
The discussion in the comments revealed that the "planned addition" as described is perfectly fine but that the only detail that really needed additional confirmation was the conduit fill calculations, specifically regarding derating.
Since I'm using a T-style conduit body to branch a raceway for two fixtures there is not room to have a code-compliant splice between the common junction box and the fixtures themselves. This then means that separate neutrals need to be pulled and that there will therefore be more than 3 conductors in the shared part of the raceway. I had initially read that derating didn't come into effect for small wires (#14 and #12) until a much higher number of conductors are involved, but it was a good exercise to truly confirm this.
The NEC requires derating for 3-or-more conductors in one raceway. My initial impression for #14 THHN was that it's rated to only 15 amps, which would then mean that any derating requirements could be an issue for this 15 amp branch circuit. Looking deeper tough it turns out that 15 amps is only the required overcurrnet protection for circuits with #14 wire (from NEC from 240.4(D)(4)) and that #14 THHN is actually rated slightly above 15 amps at low temperatures. In my case I needed to derate 80% (for 4-6 conductors), and for #14 THHN at low temps this worked out to 80% of 25 amps = 20 amps, which still appears quite fine for the existing 15 amp branch circuit that I'm working with. This handy online tool, and of course the appropriate tables from the NEC (from 310.15(B)(16)), confirmed this.
So it looks like this planned addition is fine as stated assuming a wire gauge <= #14.
Best Answer
Depending on how it's connected, and how the breakers are oriented in the panel. Yes, it could provide a 240V 20A circuit.
If this is how it's being used, then the breakers should have their handles tied together.