Does the light switch feel any different than the fan switch? The switch can feel funny if it fails.
Also, what kind of fixture it is? It's probably not relevant, but it's not a bad detail to add.
OK, looking at your diagram, I'm happy to see that all the gnd and all the neutral are tied together. That really helps, as it means you don't have anything too weird going on.
I'm going to describe what I see in that diagram, so that we're on the same page (or so that you know I have no clue).
From what you've drawn, I assume that the wire going to the light fixture is the one on the left, the fan is the one on the right.
One of the center 3 lines goes back to the breaker. The other two of the center three lines are actually branches that feed something else (basically, they are chained off of here). That big bundle of 4 wires on the one leg of the light switch are just a way to get everything tied together without a separate wire nut.
At this point, as long as all connections to the switch are good, and you think the fixture is good, then I'd say it would have to be the switch itself - they are mechanical, and they do go bad over time. If you have a multi-meter, or some kind of circuit tester, then you should be able to check the power at screws of the fan switch - the one coming from the light switch will be hot all the time, the other side will only be hot when turned on. Then try the light switch - I bet it's not actually working correctly.
If you don't have a tester, just replace the light switch. They don't cost much, and then you'll know for sure.
Corrosion isn't your problem. The screw was too long and it bottomed out on what looks like a cable clamp in the box. The screw is in compression. If you get in there with a Dremel with the tiny cutoff wheel, you should be able to saw through it. Once you do the compression will be gone and you should be able to finger-spin it out.
It looks like his mistake was using extra long screws because of the depth of the plaster there. And he went extra extra long, and was too long and bottomed out. Choose length more carefully, or use the feature on your wire stripper to cut bolts.
Best Answer
It is a
soldering aid tool
.Used for holding components down while soldering.
The slot is for manipulating wires.