How to build shelves on non-square (>90 degrees) walls

It sounds like you have a floating shelf. Because of the shear forces, these don't hold very much as they just end up pulling away from the wall.

If you want to pile heavy books on it, you are going to need to support it properly. The words "decorative" and "strength" don't usually go well together. I would think you need something solid and not a rope. With rope you have to worry about tensile strength, stretch and how to anchor it (will the anchor now hold the weight?).

The best thing to do is install a bracket below the shelf to support it. How many of these you need will depend on how long your shelf is and what it's made out of. You could always start with two (one on either end), and if the shelf is sagging, install another one in the center. There are "decorative" brackets out there but the basic principal is the same. Make sure you anchor these into a stud and not just the drywall or else you'll end up just pulling the drywall off your wall.

I've always wanted to do something with a shelf attached with cables to pulley blocks with counterweights. Kind of old school, but would do the job for you. Using counterweights is good in your situation, because the weight of the empty appliance (microwave with no food) is constant. The downside is you must spent a good deal of time designing the system to the fit and finish of your kitchen. It looks like you can get the cable and pulley blocks from amazonsupply.com.