When determining feeder conductor size, you'll want to consider the "lowest temperature rating of any connected termination, conductor, or device" as per National Electrical Code (NEC) Article 110.14(C).
While the cable/wire may be rated at 90°C, you'll likely find that the terminals are rated at 75°C, or not labeled at all. 110.14(C)(1)(a) tells us, that since we're working with 100 amperes or less. We should use the 60°C column of Table 310.15(B)(16) to determine the conductor size, unless the equipment is listed and labeled for a higher temperature.
National Electrical Code 2014
ARTICLE 110 Requirements for Electrical Installations
110.14(C)(1) Equipment Provisions. The determination of termination provisions of equipment shall be based on 110.14(C)(1)(a) or (C)(1)(b). Unless the equipment is listed and marked otherwise, conductor ampacities used in determining equipment termination provisions shall be based on Table 310.15(B)(16) (formerly 310.16) as appropriately modified by 310.15(B)(6).
(a) Termination provisions of equipment for circuits rated 100 amperes or less, or marked for 14 AWG through 1 AWG conductors, shall be used only for one of the following:
(1) Conductors rated 60°C (140°F).
(2) Conductors with higher temperature ratings, provided the ampacity of such conductors is determined based on the 60°C (140°F) ampacity of the conductor size used.
(3) Conductors with higher temperature ratings if the equipment is listed and identified for use with such conductors.
(4) For motors marked with design letters B, C, or D, conductors having an insulation rating of 75°C (167°F) or higher shall be permitted to be used, provided the ampacity of such conductors does not exceed the 75°C (167°F) ampacity.
Since the cable will run from a breaker in the main service panel, to either a breaker or lugs in a subpanel. We have to consider the temperature rating of...
- The conductors
- The terminals in the main panel where the conductors will connect.
- The terminals in the sub panel where the conductors will connect.
We'll then use the lowest value, or 60°C if any of the above are not labeled. Once we know the size of the overcurrent devices, and the lowest temperature rating, we can use Table 310.15(B)(16) to determine the conductor size and material we'll need.
This will give us the current carrying conductor size required for our feeder.
But wait...
If you're working in a one-, two-, or multi-family dwelling unit, is Article 310.15(B)(7) applicable?
National Electrical Code 2014
ARTICLE 310 Conductors for General Wiring
310.15 Ampacities for Conductors Rated 0–2000 Volts.
(B) Tables. Ampacities for conductors rated 0 to 2000 volts shall be as specified in the Allowable Ampacity Table 310.15(B)(16) through 310.15(B)(19), and Ampacity Table 310.15(B)(20) and Table 310.15(B)(21) as modified by (B)(1) through (B)(7).
The temperature correction and adjustment factors shall be permitted to be applied to the ampacity for the temperature rating of the conductor, provided the corrected and adjusted ampacity does not exceed the ampacity for the temperature rating of the termination in accordance with the provisions of 110.14(C).
(7) 120/240-Volt, 3-Wire, Single-Phase Dwelling Services and Feeders.
(a) For individual dwelling units of one-family, two-family, and multifamily dwellings, conductors, as listed in Table 310.15(B)(7), shall be permitted as 120/240-volt, single-phase service-entrance conductors and service lateral conductors.
NO.
Notice the codes says
"shall be permitted as 120/240-volt, single-phase service-entrance conductors and service lateral conductors".
After reading the definition of these terms, it's clear that this does not apply to the wire between the main panel and a subpanel.
Service-Entrance Conductors, Overhead System. The service conductors between the terminals of the service equipment and a point usually outside the building, clear of building walls, where joined by tap or splice to the service drop or overhead service conductors.
Service-Entrance Conductors, Underground System. The service conductors between the terminals of the service equipment and the point of connection to the service lateral or underground service conductors.
Service Lateral. The underground conductors between the utility distribution system and the service point.
tl;dr
Conductors and all terminals rated at or above 75°C.
Use 3 AWG copper or 1 AWG aluminium for the current carrying conductors.
Conductors rated at or above 75°C, terminals rated at 60°C or unlabeled.
Use 1 AWG copper or 1/0 AWG aluminium for the current carrying conductors.
Conductors and terminals rated at 60°C.
Use 1 AWG copper or 1/0 AWG aluminium for the current carrying conductors.
Conductors rated at 60°C, terminals rated higher than 60°C
Use 1 AWG copper or 1/0 AWG aluminium for the current carrying conductors.
Best Answer
The most important aspect of speaker wire is resistance. There is a ton of junk-science and stupid audiophile marketing claims that will try to confuse you and make you spend absurd amounts of money, but don't be fooled.
Wikipedia actually has a good write-up on it:
They also have a chart: for 35' at 8Ω, you're good with 18 or 16AWG.
All you need is basic stranded cable. Don't pay extra for fancy brands, or "oxygen-free" or "hand woven by the dalai lama" or whatever (unless you have the money to burn and really way to, I guess) as there's really no difference -- you can use lamp cord, if you want.
In proper tests, the best audiophiles can't tell the difference between $500/ft "top of the line" speaker wire and coat hangers -- and if you can, James Randi will give you $1 million (sorry, a bit OT from your question, but people that believe in this nonsense really piss me off).
For in-wall applications, you should get wire rated for in-walls - which basically boils down to fumes that the wire gives off in a fire. There's a good article on Understanding In-wall Speaker, Video and Audio Cable Ratings on Audioholics. In short, in a 1-2 family dwelling, any cable with the following ratings is suitable for in-wall: CM, CMP, CMR, CMG, CL2*, CL3*.