For Cambridge Dictionaries Online, at least, part of the answer may be to do with syllabification. First note that the transcriptions are phonological, as indicated by the slashes //, not phonetic, which would be indicated by square brackets []. That means that the phonetic realization might be identical even if the phonological representation is different (for any given speaker).
The generalization seems to be that the sound is represented as a /j/ if it is in the onset of a syllable, but as /i/ elsewhere. For instance:
- pantheon: /ˈpæn.θi.ən/
- grammarian: /ɡrəˈmeə.ri.ən/
- Paralympian: /ˌpær.əˈlɪm.pi.ən/
vs.
- Italian: /ɪˈtæl.jən/ (with /-i.ən/ given as an alternative)
- minion: /ˈmɪn.jən/
- onion: /ˈʌn.jən/
and
- galleon: /ˈɡæl.i.ən/
- bullion: /ˈbʊl.i.ən/
- Euclidean: /juˈklɪd.i.ən/
- Syrian: /ˈsɪr.i.ən/
In the first set of words, the sound is not in the onset of the syllable, but in its nucleus. In English syllabification, the nucleus must be vocalic. In the second set, the sound is in the onset. Since in English syllable onsets must be consonantal, it has to be represented as /j/. In the third set, the /i/ is in a syllable on its own, and hence is the nucleus of the syllable.
Words with only one consonant before the /i/ or /j/ can be divided into either two syllables or three (as /ɪˈtæl.jən/ vs. /ɪˈtæl.i.ən/ shows). Words with two consonants before the sound can only be divided into three syllables with /i/ as nucleus, since English syllabification prefers to balance consonants across syllables in certain ways. So /ˈpænθ.jən/ is not a well-formed syllabification.
As for whether there is a genuine contrast between champion and million, I think there may be in some instances. I can pronounce the latter either as /ˈmɪl.i.ən/, with three syllables, or as /ˈmɪl.jən/, with two, but /ˈtʃæmp.jən/ just sounds wrong to me. YMMV, though.
Glottal stop, according to the following article:
The glottal stop or glottal plosive is a type of consonantal sound used in many spoken languages, produced by obstructing airflow in the vocal tract or, more precisely, the glottis. (Wikipedia)
From The New York Times- Connecticut - Accent? What Accent?
"It's called a glottal stop," said Pat Gomola, a speech pathologist at the Speech and Language Institute in Middletown. "It's not a 't' sound. You say it in the back of your throat. It's the same thing when they say double-t words like cattle or bottle." In New Britain, such words come out as "CAH-uhl" or "BAH-uhl."
Ms. Morgenstern attributed this sound to New Britain's large Polish-American population. "They don't enunciate their consonants as much," she said.
Best Answer
Some parts of the South, including the part of Kentucky I grew up in, "here" gets pronounced in the UK manner with the schwa and without the 'r' (and as two syllables), while "hear" gets pronounced in the US manner without the schwa but with the 'r'.