Both the Oxford English dictionary and Merriam Webster give the definition of "pop" (singular) to mean "father" in an informal manner and give "pops" to be the plural form of pop, thus "fathers".
If I am not mistaken, however, many Americans seem to use "pops" in a singular sense to call their own fathers. I only found two online sources that support what I heard, but I am curious if people on this forum can share more information.
- father (Dictionary.com)
This link for Wiktionary has an article about father with the title "Dad? Pops? Father? Why are there so many name for the same person?"
This source simply defines "pops" as "father" (singular).
Best Answer
According to the OED, the s in pops is:
Also, the earliest citation in the OED for pops is from 1893:
(In comparison, according to this answer, toots is first attested in 1891.)