What's the difference between those terms? Can they be used just about interchangeably?
road: a long, narrow stretch with a leveled or paved surface, made for traveling by motor vehicle, carriage, etc.; street or highway. Random House Kennerman Webster's College Dictionary
pavement: n. (Chiefly AmEng) A hard smooth surface, especially of a public area or thoroughfare, that will bear travel. American Heritage® Dictionary
roadway: n. A road, especially the part over which vehicles travel.
American Heritage® Dictionarychaussée: nf (voie de circulation) road n; (US) pavement n; roadway n
Il y a des nids de poule sur la chaussée, fais attention !
There are potholes on the road [surface], be careful! WordReference
Best Answer
They are not quite the same.
Road refers almost exclusively to something use for the travel of motor vehicles as the definition you quote says.
Pavement is a hard surface, almost always for travel of some kind, but sometimes other things.
For most kinds of road the terms could be used interchangeably, but there are exceptions. Let me give examples to illustrate the difference.
Roadway is not common, but I would use it to refer to the parts of a road on which travel actually occurs - so excluding medians or shoulders that might be considered part of a road.