Merriam-Webster's Eleventh Collegiate Dictionary (2003) has the following entry for BB:
BB n (1845) 1 : a shot pellet 0.18 inch in diameter for use in a shotgun cartridge 2 : a shot pellet 0.175 inch in diameter for use in an air gun
The two definitions incorporate more-precise measurements than are likely to have been applied back in 1845, when MW says the term was first used in print, and this suggests to me that there may have been a significantly simpler definition (such as "small birdshot") back in the earliest days of the word's use. Also, the 1845 origin date notwithstanding, the first edition of the Collegiate Dictionary to include any entry for BB was the Eighth Collegiate, published in 1973.
The full-size Merriam-Webster's Third International Dictionary (1986) repeats the definitions of BB (which it gives as "bb or beebee … usu cap both Bs") from the Eighth Collegiate and then offers this rather cautious speculation about the term's origin:
[prob. fr. the letter b]
This doesn't strike me as being very informative.
Stuart Miller, Concise Dictionary of Acronyms and Initialisms (1988) has this brief entry for BB:
BB Shot pellet
The Compact Edition of the Oxford English Dictionary (1971)—the edition with the magnifying glass—has no entry for BB at all. The Online Etymology Dictionary doesn't cover the term either.
The closest thing to an explanation that I've found so far is in Wikipedia's entry for "BB gun", which states:
The term "BB" originated from the nomenclature of the size of steel balls used in a shotgun. BB sized shot was normally 0.180 inches (4.6 mm), but tended to vary considerably in size due to the high tolerances in shotgun shells. The highest size shotgun pellet commonly used was named "OO" or "double ought" and was used for hunting deer and thus called "buckshot."
Around 1900, Daisy, one of the earliest makers of BB guns, changed their BB gun bore diameter to 0.175 inches (4.4 mm), and began to market precision-made lead shot specifically for their BB guns. They called these "round shots", but the "BB" name was already well established, and everyone continued calling the guns "BB guns" and the shot "BB shot" or just "BBs".
This discussion corroborates the Eleventh Collegiate's measurements for pellet diameter, and it suggests a first occurrence date for definition 2 of BB of "around 1900," when Daisy standardized the size of the lead pellets for its BB guns at 0.175 inch in diameter. But it doesn't address the origin of "BB" as a classification name, including whether it originally stood for some longer word or words, nor does it indicate whether BB is older or younger than such other birdshot classifications as FF and TT.
The "Shot" subsection of Wikipedia's entry for "Shotgun" notes that current U.S. standard birdshot sizes include (from largest to smallest) FF, F, TT, T, BBB, BB, B, and 1 through 9. It doesn't offer any insight into how, where, or when these classification names originated. Neither does the "Birdshot" subsection of the Wikipedia entry for "Shotgun shell".
I have three questions about BB in the sense of a shotgun or air-gun pellet:
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What (if anything) does BB stand for?
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What was the source and original meaning of the term?
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When and where did it first appear in written English?
Best Answer
Question 1. The initialism 'BB' stands for 'bulleted breech' (also found in the form 'bullet breech').
Question 2. The source and original meaning of the term center on the circa 1845 invention of a bulleted breech percussion cap by Louis Nicolas Auguste Flobert. This 'BB' consisted of a piece of lead shot (the bullet) set into the open end (the breech) of a modified percussion cap:
(From Pistols: An Illustrated History of Their Impact, Jeff Kinard, ABC-CLIO, 2003.)
The evidence from Pistols: An Illustrated History of Their Impact is corroborated by numerous other sources revealed through searches of Google Books for 'bulleted breech', 'bullet breech', and those terms with the addition of 'BB'. Examples include these:
(From The Complete Book of the .22: A Guide to the World's Most Popular Guns, Wayne Van Zwoll, Globe Pequot, Aug 1, 2006. See also other mentions in this book of "bullet breech" and "bulleted breech".)
(From Cartridges of the World: A Complete and Illustrated Reference for Over 1500 Cartridges, Frank C. Barnes, Gun Digest Books, Sep 22, 2009.)
The commonly cited 1845 date for the invention of the 'BB' Cap coincides with the earliest quote for 'BB' appearing in the OED:
["BB, n.". OED Online. September 2015. Oxford University Press. http://www.oed.com/view/Entry/251187?rskey=GeHVuV&result=2&isAdvanced=false (accessed November 15, 2015).]
Question 3. My research did not reveal any pertinent use of the initialism earlier than the 1845 OED quote reproduced in full above. In light of the date other sources give for the invention of the BB round by Flobert, it's unlikely that earlier written instances exist.
I did run across one source, the Bulletin of the Oklahoma Anthropological Society (Volume 45 Oklahoma Anthropological Society, 1996) that dated the BB load to 1831. Given the complete absence of support for that date, my assumption is that the 1831 date is a simple factual error.
Before finding abundant evidence of the actual source of the initialism, my research set me off on several wild goose chases, including one that led me to hypothesize that 'BB' might refer to 'Big Bird':
(From Terminal Ballistics: A Text and Atlas of Gunshot Wounds, Malcolm J. Dodd, CRC Press, Oct 31, 2005.)