An unmarried male is called a bachelor. Is there an English word for an unmarried female?
Learn English – the word for an unmarried female?
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A jenny.
People have used "sistern" for this. The first use I find in Google books is from 1739:
That there were 20 Bretheren and Siſtern on their Bead Roll,
I suspect this plural was invented to serve as a parallel to "brethren"; I did not find it in the dictionaries I checked, and it is a much rarer word than "brethren".
UPDATE: as Unreason points out, I did not find it in dictionaries because it is currently spelled "sistren"; although until its recent revival around 1980, the spelling "sistern" was just as common (these are presumably also pronounced differently). Both forms are derived from the Middle English plural of "sister". Google Ngram:
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