I remember some mini boss in a DLC drops one, or has a chance too. Doc Mercy just isn't dropping it for me.
Borderlands – ny other boss that drops the Infinity gun
borderlands-2
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Best Answer
Any legendary has a 1/20 (5%) drop rate from the boss it's assigned to, the infinity pistol is assigned to Doc Mercy. Any legendary has a 1/1000 (.1%) to be found in a chest, random drop, or in a skag/stalker/whatever pile.