I've been trying to get a Jolly Solgaleo leading with a synchronize jolly Abra, but it's been my 12th attempt and Solgaleo is anything but Jolly. Did they remove this mechanic in gen7?
Can you guide Solgaleo’s nature using Synchronize lead
pokemon-sun-moon
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Best Answer
Looking at some threads, like this one or this one, it seems that it is totally possible to synchronize the nature of Solgaleo.
The fact is that the Synchronize strategy only has a 50% chance of working. So it is totally possible that, even on your 12th try, you are being really unlucky. Try some more times, and you will end up getting your Jolly Solgaleo.
So no, this mechanic has not been removed in Generation 7.