I currently have over 100 regular arrows after purchasing them from the stores. I've now waited until after a Bloodmoon and the arrows still have not respawned in shops. I've tried purchasing other items and they seem to respawn fairly quickly, but not arrows.
Zelda Breath of the Wild – Unable to Purchase More Arrows
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Best Answer
Arrows will only respawn in shops if you have less than 50 arrows of that type (e.g. Normal, Fire, Bomb, etc).
As such, the best method to stock up on arrows from shops is to use up arrows until you have 49, then buy arrows from all the shops at once.
The only exception to this is Ancient Arrows