Diablo – What’s the highest DPS Wizard rotation for a single-target fight

For the Critical Mass passive, what is meant by the "chance" is that it is determined by the proc coefficient of the spell you cast. Single target spells have 100% "chance" to reduce the cooldown by 1 second while AOE spells have differing sets of proc coefficents by spell AND rune. There's a few sites that break down proc coefficents of various spells which applies to crit chance as well as return on LOH. Here, and here. Luckily people with more patience than me seem to have most spells crit proc chance figured out.

Some useful proc chances for popular wizard spells:

Hydra: 0%, Hydras never proc
Magic Missile / Seeker: 100%
Shock Pulse / Piercing Orb: 25% per target hit
Blizzard / Snowbound: 2% per tick per target hit
Energy Twister / Wicked Wind: 10% per tick per target 
Explosive Blast / Chain Reaction: 11% per target hit per explosive (of 3)

I've recently been trying the Windup Wizard/CM build which still seems pretty effective, and a bit silly (in fact it was the easiest way for me to beat inferno Ghom). From personal experience I've found that on my wizard, when I run over 40% crit chance while using a build like windup wizard, everything is off cooldown pretty much all the time.

From the standpoint of your weapon: Weapon Damage is king. Above all else, you want the highest possible amount of raw damage and DPS possible. Beyond that, you'll want to take a look at this formula to understand the value of other stats.

In short: at low levels, nothing is going to beat raw +Damage on any slot where you can get it (Rings, Neck, Offhand). As you increase in level, you'll eventually reach a point of inflection where the multiplicative scaling gained from adding +Dex is more valuable than the straight + Damage. This point of inflection will vary with other stats, and particularly with the base DPS of your weapon - your best bet is to simply keep an eye on the +Damage portion of the tooltip when comparing items.

As for stats like Crit and Attack Speed, the same basic rules apply. In general, .1 attack speed is worth 10 Dex, but this ignores the defensive benefits of Dexterity, and since attack speed bonuses are provided as percentage multipliers, you'll need to do some math. You'll need to run similar calculations with +Crit and +Crit Damage, but in general, unless you use skills or passives that rely on Crit, you can assume those stats are less valuable than the others.

Really, all of this comes back to one key point: Trust the Damage Stat on your Character Sheet. So long as you're doing the basics right (using a level appropriate, high DPS weapon), it isn't going to steer you far wrong. Beyond that, Dexterity is King, and everything else depends entirely on the magnitude of the stat that you get. An item with +Crit might be better than an item with +Attack Speed, based purely on how much of it is there.