Find an Ebony Helmet

Daedra hearts are a rare drop from Daedra mobs: Atronachs and Dremoras. They will not drop from conjured Daedra, though: so no farming your conjured servants. Good places to find Daedra are during the Daedric quests The Black Star and Pieces of the Past.

In addition to that:

• One can be stolen from the Nightcaller Temple in the Daedric quest Waking Nightmare
• One can be stolen from Kodiak's room in Jorrvaskr in Whiterun
• Enthir in Winterhold College sells 2 every 48 hours at a huge premium
• They will rarely show up for sale on random vendors throughout the world

The Wikia suggests a few other places as well:

• Alchemists in Orc Camps will sell 2-3 of them
• Babette at the Dark Brotherhood Sanctuary
• One at Hall of the Vigilant directly south of Dawnstar and near Red Road Pass where a giant exists
• Random chance to be on any of several vendors in Markarth Side

You can use the Dead Thrall spell to repeatedly kill just one NPC who trusts you, instead of having to kill many different ones.