I know you have to go to Lumiose City, but I'v been there a lot of times and Looker hasn't called yet.
How to trigger the Looker event in Pokemon x and y
pokemon-x-y
Related Solutions
The kanto starters are available through the friend safari, assuming you have friends of the fire, water, or grass types. You'll find them in their middle evolution. i.e, ivysaur.
Here is a picture from (what I think is) the official Pokemon X&Y Guide.
Every little thing you do in Lumiose City adds to your style. Stylishness brings all kinds of rewards, such as meeting various characters, getting discounts, and unlocking facilities and fasions.
Good luck fellow trainers :)
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Best Answer
You must be a Champion (beat the Elite Four and champion then resume playing), get the Mega Ring upgrade by doing a Battle Mansion event then battling your rival and meeting Sycamore in Anistar City, and then visit Lumiose City again. Looker called me almost immediately after entering the city, and reentering the city will usually trigger his calls to start the next "chapter" of Looker events.