Is there a way to put someone in a black list, so they can't play with you again ?
League-of-legends – black list other players
league-of-legends
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Best Answer
In addition to ignoring the person, you could report them for "Unskilled Player". Unskilled player reports never go to the tribunal or result in a ban, but are only used for determining matchmaking [1].
This will not result in a blacklist, but will help to minimize the chance of them being randomly queued with you.