You're right. The best way to use Zhonya's Hourglass is by using it in a teamfight. Lightning Rush in, try to hit as many targets as you can, then activate Electrical Surge, then Slicing Maelstrom. Here is the description for Kennen's ultimate, along with the description for Zhonya's hourglass, from the League of Legends wikia page.
Kennen summons a magical storm that deals magic damage to a random enemy champion near Kennen every 0.5/0.4/0.33 seconds. The storm hits several times, increasing with level, and cannot hit the same target more than 3 times. A Mark of the Storm is applied to enemies each time they are hit.
Unique: Places your champion into stasis for 2 seconds, rendering you invulnerable and untargetable but unable to take any actions. 90 second cooldown.
- At level 6, You can get four Marks of the Storm.
- At level 11, You can get five Marks of the Storm.
- At level 16, You can get six Marks of the Storm.
Add this to your two marks of the storm on each opponent with your E-W combo, along with any Marks of the Storm added from your ultimate before using Zhonya's hourglass. You can potentially stun all opponents.
Since Kennen's ult is very powerful due to its utility, enemies will try to focus you down to avoid stuns. That's when you want to Zhonya's. When it's active, you will continue to stun enemies.
Rammus' great strength comes with the element of surprise. If Rammus isn't in your face, and he isn't powerballing, then he's not scary.
First, the general Powerball gank-tip: start charging it before you actually go in to gank. It takes some time to get spinning, but lasts for quite awhile. If you just press Q and charge on in, you give your opponent precious escape-time. Figuring out the timing on this is critical.
Second, wards. Namely, destroying their's. Rammus late-game can be something like Fiddlesticks; if you can get the jump on them from a surprising position, you've really got something. Have an oracle's on your team (either you or your support) and clear out those wards. Leave them guessing.
Third, scaling MR blues. Rammus needs MR, and these provide a healthy chunk.
Fourth, effective team communication. When Rammus goes in, he goes in. He isn't getting back out. If your team is not prepared to jump in after you, you're going to have a bad time.
Fifth, make use of your early-game advantage. Rammus is FRIGHTENING during the laning phase. If you manage your Powerball correctly, and your lanemate has any CC at all, you're pretty much guaranteed a kill. Gank frequently.
Sixth, give your lanemates the kills, whenever and wherever possible. Don't ever let a kill get away, but if the opponent is certain to drop, give it to your lanemate. They can put that extra gold to much better use.
Talon is very good at farming. Level up his rake(W) as fast as possible to 5. This can essentially one shot a minion wave. Many people at lower levels do not understand the importances of balancing harassing with farming. Farm up well early game, dominate late game.
If Talon is laning with a partner, choose a partner with good crowd control. Talon can easily harass with his rake while still farming. Just use it while the enemy is standing by the minions you are trying to kill. When an enemy is low enough, get the partner to stun or snare and you can cutthroat in and use to burst to bring down the enemy. Note that cutthroat will not only increase your damage but silence the enemy so that they cant ghost/flash or use one of their spells to escape before you kill them.
If talon is laning top solo, once again focus on leveling up rake and farming with it. But with talon being alone he can harass more aggressively by using cutthroat to silence the target, use your skills and run away before the silence ends. This usually results in you dealing a lot of damage to the enemy than they can retaliate with.
When to engage:
I assume you mean in a teamfight. There are two ways to play talon in teamfights. The first way is to play like a normal assassin and stay behind your team hidden. Only when the team's initiator(tank/offtank) go in and the fight has started so you go in and focus their ap carry. I say this because talon has a silence which will prevent their ap carry from doing any damage.
Another way to play him that most people are usually reluctant to do is be the initiator. This will work really well if the opposing team does not have too many stuns and/or do not have oracles. You basically cutthroat into their ap carry and immediately ult to stealth. This will cause them to immediately switch to another target(preferably your tank/bruiser who has come in by now). A benefit of this is, you get to damage everyone with the beginning of your ult AND the end of your ult.
Talon is as I've said before a burst assassin. He bursts and then runs off. So if anyone ever tells you to built attack speed on him. DON'T. Build pure AD and armor pen on him. You shouldn't have to stay and autoattack because any tanky AD DPS can kill you in a toe to toe fight
I would start with dorians blade first. At first recall, hopefully enough gold to buy a pair of boots and the brutalizer. Next built the boot into Ionian Boots for the CDR (Once again berserkers's attack speed is less desirable compared to CDR where you can burst more often), and start of the blood thirster. Then i would finish the brutalizer into Youmuu's GhostBlase and bloodthirster. Afterwards i would built last whisper (that 40% armor pen is OP!) Infinity Edge and Another Blood Thirster to finish.
Runes: When runing a champions there are two things to keep in mind. Do you normally have trouble early game and would like a early game advantage or do you do well early game and want to have runes that scale really well into late game.
If you do not do very well early game and need all the advantage you need, then build flat AD Marks. But if you do well and want runes to scale better late game, built Armor Penetration Marks.
For Seals, I would take flat mana regen(replenishment) because talon is pretty mana starved early game if he wants to farm well and still harass.
For glyphs i would take flat cool down reduction.
And for Quintessances, i would take Armour Pen.
With the new change to the mastery trees, assassins like Talon can rejoice! I won't tell you exactly which to put points into but focus on the offensive tree for assassin champions like talon who focuses on burst.
Summoner Spells: The two I would recommend is: Ignite and Flash. Flash is of course one of the most powerful summoner spells there is. This can be used both offensively and defensively. If the enemy is just out of reach of your cutthroat and you can't jump to them for the finishing blow, flash will close the gap between you. Or defensively you can use it to create a greater gap between you and your enemy OR flash over a wall. You do not understand how many times that has saved my life.
Ignite's DOT and his Q's DOT does a surprising lot of combined damage. In addition ignite will reduce the amount of healing the opponent have/gets. So if you are laning against someone with heal or a lot of life steal, ignite will make you laugh gleefully as they die because they can't heal themselves from your burst.