Why can't I disenchant the Arch-Mage robes?
The enchantment on the Arch-Mage robe
the-elder-scrolls-v-skyrim
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Best Answer
Most Unique items that have a unique enchantment on them cannot be disenchanted, to stop people from adding overpowered enchantments to high level armor.
You can see here what the enchantment actually entails.