Does anyone knows what buff is that from the screenshot that character's top orange symbol icon?
Path of Exile – What Buff Is Represented by the Orange Symbol Icon?
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Best Answer
The orange lady above the character's head signals that a flask with the suffix "of Warding" is currently active, which makes your character immune to curses during the effect, see wikia entry.
The symbol for this buff is the purple picture showing the figure with the X above it's head, as seen in the other answer.