According to this official documentation the platform-show-toast-event component/event is unsupported in LWR site.
According to this official sample LWR site a showToast event is utilized (see line 76 of footerMenuItem.js)
These are conflicting each other and I'm wondering whether showToast can be used in LWR?
Best Answer
Note that from the Summer '23 release, you can use https://help.salesforce.com/s/articleView?id=release-notes.rn_lwc_toastcontainer.htm&language=en_US&release=246&type=5