Yes, they can be, but you'll want to prick each one with a sharp knife once or twice to prevent them from bursting. Once that is done, put them into a small freezer-safe storage bag, remove as much air as possible from the bag, and seal it. They keep reasonably well for about six months without tasting "burnt," but they tend to be a tad mushy upon defrosting.
I always thought the mushiness factor had to do with length of freezing time, but since you asked, I did a bit of research. Apparently, what makes chilies turn to mush actually has to do with how quickly they initially freeze:
The undesirable mushy end product that comes from freezing fruits and vegetables isn't from the act of freezing itself, but from how you freeze. Your ordinary freezer, or even deep freezer, freezes food slowly. Chilies have water in their membranes, and as they slowly freeze, it forms jagged ice crystals that pierce and puncture the membrane, so that when you defrost it, you're left with a leaky and "tenderized" result. The solution to this problem is easy … faster freezing. If the water doesn't have time to form jagged ice, you won't have a mushy membrane.
Happy Living (from which I pulled the above quotation) has an article about how to safely use dry ice to freeze chilies quickly. (I'll probably keep going the way I always have and accept the mushiness, but if you want to freeze a lot of chilies for a variety of applications, the dry-ice method looks promising.)
You can't drain them while they're frozen. If you need to use them quickly, consider thawing them in the microwave, then draining them.
As for how to drain them, it depends on the type of vegetable. Greens like spinach should be squeezed out. Chunky vegetables should be drained in a colander and then dried with a towel.
Some of the water you get may be coming from inside the vegetables, though, in which case it's still going to come out only when cooking. In that case, the only solution is not to overcrowd the pan.
Best Answer
Yes, you can, but ideally you should roast them first. I would peel them as well. You could leave them otherwise whole if you wish, to give you greater versatility when you defrost them. If you roast, peel, de-seed, then freeze, you could even make a passable (not great, but passable) Chile Relleno out of the not-quite defrosted pepper. Stuff and bread them while still partially frozen and they'll be easier to work with.
Here's an article on the subject from The Kitchn.