Is it better to add fresh basil to a tomato sauce and then let it cook for say, 10 mins, or wait till the end and add just before serving?
When to add fresh basil to a tomato sauce
basilitalian-cuisine
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Volume measurements of herbs are hopelessly imprecise to begin with; what you actually measure as 1/4 cup depends entirely on how tightly you pack them, how wet the leaves are, even the size/shape of your measuring cup or spoon. When given a measurement like that, you should always treat it as a rough guideline; don't worry about being exact, it's not necessary in this recipe.
That said, what it actually means is that you should measure out the 1/4 cup and then shred them. Another example of this type of language is when you see something like "4 tbsp of vegetable oil, divided" - that always means you measure out the 4 tbsp and then divide into two portions, not measure out two separate portions of 4 tbsp each.
So measure it first, then shred it. If you were supposed to shred it first, it would say "1/4 cup shredded fresh basil leaves" instead. There is an appreciable difference as to how much basil you'll end up with, but again, you've been given a very rough measurement to begin with, so treat it accordingly, and don't worry if you've got a little extra or a little less. The most reliable way to know if you've got the right amount is to simply taste it.
I have noticed that basil changes its taste as it ages, but not as to get bitter. On the other side, I like a bitter taste, so I often overlook (overtaste?) bitter notes to which other people show a strong reaction. Try getting some fresh basil and comparing the taste/aroma of the fresh and the old one, maybe it is really just the aging difference you perceive as unpleasant. I regularly use the stems when I have fresh basil.
Generally speaking, you cannot deceive your brain to not perceive bitterness (unlike sourness, which is counteracted by sweetness - the pH value of Coca Cola (2.6) is lower than that of tomato juice (4.1), but the soft drink is perceived as sweet, not sour). But if you mix it with another basic taste, the combination might feel much better than the pure bitter taste. The other strategy would be to just dilute with something bland, in order to reduce the bitterness intensity. Most adults actually like some bitterness if it is not too intense. The third option would be to use something with a very strong flavour to mask everything, e.g. add lots of raw onions and/or garlic, or just make it so hot you don't actually pick up much of a taste. I am not a fan of this solution, but your mileage may vary.
As for a taste combination, which taste should you pick? Strangely, people tend to think that a sweet taste is well suited to somehow "mask" bitterness, which I cannot confirm. For me, both tastes, bitter and sweet, stay there, and one doesn't mask the other, they just create a specifically unharmonious combination. In my experience, bitter + sour is a much better combination (think grapefruit, cranberries, or tonic water) which can even allow for a small amount of sweetness, without making it clash. But it is also good to make a combination of bitter + salty taste. While umami can be combined with bitter too, it doesn't diminish the unpleasant sensation of the too bitter.
As for your specific problem, I often eat basil dips, only I tend to base them on feta cheese. I sometimes add sour cream or other dairy products, but usually less sour cream than cheese. I think that it will be a good solution for your problem, as it will both complement the bitterness with a strong salty taste, and dilute the bitterness concentration as you will be using lots of it. I also almost always add lemon juice (should help for the bitterness too) and a dash of olive oil (which shouldn't affect the taste, only the aroma). Another ingredient which does well in a basil dip are green or blonde olives, if their salt level is not too high.
For a basil dip, I usually throw everything in a bowl and smooth it with the immersion blender. If you aren't sure that you'll like the taste, try tasting a spoon of your current dip with a small piece of feta and/or an olive before committing more ingredients to something you'll ultimately throw out.
Best Answer
Fresh herbs should, generally, be added closer to the end of a recipe. Dried herbs should be added fairly early on during the cooking process so that they have time to "develop" and more fully release their flavors. Fresh herbs and spices, however, will generally have more subtle flavors, and they are usually best used for seasoning at the very end of the recipe, rather than actual cooking. You can check out more details about how to use different kinds of spices in this article.
For your specific case, I would say to definitely add the basil in at the end—maybe five or ten minutes before the sauce is finished, as you said. It may even be a good idea to remove the pot from your heat source after you have added the basil so that the herbs can infuse their flavor without actually cooking into the sauce. You have to be careful not to cook too much of the flavor out with fresh herbs. If they simmer too long with the rest of the dish the subtle flavors can be easily overpowered by other ingredients.