I'm sure there's a word which matches this definition. Where you make a slight mistake in saying something and a friend will nudge you and say "oh, so that's what you really think?!"
One example, though not perfect, was when Prime Minister Gordon Brown, in a heated exchange, meant to declare "We saved the banks" but actually said "We saved the world…" before correcting himself.
Best Answer
That's an example of Freudian slip (wikipedia):
It is also known, technically, I suppose, as parapraxis (dictionary.com):