By chance, I told him where I learnt chaos magic ( chaos covenant ), but I didn't learn all spells from him, is there any possibility to learn it somewhere else ?
Dark Souls P2DE: Trainer Laurientus
dark-souls
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There's also Rhea of Thorolund whom you rescue from Tomb of the Giant. If you rescue her, and then proceed to kill Petrus of Thorolund right away, she will sell you miracles in the Undead Parish Church until you buy all of them.
I'm really not so sure what you're talking about either...are you referring to the Dark Knights?
If so, these guys are pretty powerful at the point of the game you're at - they're placed in locations that you can easily avoid, so for the moment you can run past them and come back to fight once you're stronger.
They also don't respawn so you don't need to worry about having to fight them again after you take them down once.
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Best Answer
The majority of his spells should also be obtainable by the chaos convenant's trainer (The egg burdened outside the firekeeper) and from The advanced trainer after training your pyromancy flame is ready to be ascended (+15). The advanced trainer is found in blight town sitting next to a pillar directly straight from Quelaags Domain's entrance.