Short question is: Why does Confusion make an Exeggutor an A grade defender, while Zen Headbutt makes it only a B grade defender?
I used to think that the most powerful charge move is the best defender and attacker move, but it turns out that while it is likely to be the best attacker move, it may not the best defender move.
The 50% or sometimes even the 33% charge move might be a better defender charge move than the 100% ones. From what I can tell, this is because if the attacker can dodge once for the 100% charge move, then the attacker has more time to do fast attacks without worrying about dodging, likely getting in at least one more charge move than the defender, which can probably finish it off.
So in this case, Psychic and Seed Bomb are probably better defending charge moves than Solar Beam. However, according to GamePress which states that 50% moves are usually better, it says if an Exeggutor has Confusion, then it is an A grade defender, regardless of its charge move, while if it has Zen Headbutt, then it is only B grade.
That same source stated that if an Exeggutor has Zen Headbutt + Solar Beam, then it is A grade attacker, but if it is Confusion + Solar Beam, then it will become a B grade attacker, which is the exact opposite of the defender case.
Do players with lots of battle experience know whether or not this is true and if so, why it is?
Best Answer
The reason "low DPS" moves are better is not because they are low DPS. And in fact, not all low DPS fast moves are better for defending; it depends on the move.
It's because, with the attack speed penalty defenders suffer (as discussed in Venomous' answer), they are actually higher DPS. This is true both for fast moves and charge moves.
A generic example might be the following. (These numbers are taken from a calculator I have, and I'm not sure they're right, but they give the right idea anyway.)
Let's say we have a pair of Slowbros. One has Confusion, one has Water Gun. Water Gun does 6 damage every half second, for 12 DPS (ignoring STAB for now). Confusion does 15 damage every 1.5 seconds, for a 10 DPS (again ignoring STAB, and rounding).
Now add the 1.5 second delay. Water Gun now does 6 damage every two seconds, or 3 DPS, while Confusion does 15 damage every three seconds, or 5 DPS. Confusion is now clearly the superior attack for a defender.
Another consideration that some of the calculators take into account is energy. If a move generates more energy, it's better (since you get more charge attacks). But again, fast moves are penalized by the 1.5 second delay here too. So a move that gives higher EPS on offense will now give a lower EPS bonus on defense relative to the other attack; so if the DPS calculation you're looking at actually includes EPS as part of it, that may be relevant.
Now, the same for Charge Attacks, for completeness:
Let's say we have a pair of Blastoise. One has Hydro Pump, one has Flash Cannon. According to my calculator, Hydro Pump has a DMG of 90, DPS of 23.7, which means it takes around 4 seconds to fire. Flash Cannon has a DMG of 60, DPS of 15.4, meaning it takes around 4 seconds to fire. Both have Water Gun as their quick move, which has a DMG of 6, DPS of 12, so it takes 0.5 seconds to fire.
For a defender, though, these numbers are a bit different. Hydro Pump now takes 5.5 seconds to fire, as does Flash Cannon, and Water Gun takes a whopping 2 seconds! So now look at their stats:
Hydro Pump is still better of course, but it is fired one time for every three times Flash Cannon is fired. That one time you get a +13 DPS, but Flash Cannon gives you +8 DPS three times. Thus, you're really comparing 13 to 24 (over 5.5 seconds of course).
On Offense, meanwhile, your Flash Cannon only had a tiny 3 DPS advantage over Water Gun, while Hydro Pump has a huge 11+ DPS advantage. So those three Flash Cannon firings give you +9 DPS while one Hydro Pump is over 11. Hence, hydro pump being the better move. (If you're a dodger, it's an even bigger advantage, as you have less time that you can't dodge, by the way.)
Now, I'm simplifying this some (ignoring STAB for one, which makes Hydro Pump better), but this gets the gist across: on defense, the DPS calculation is different due to the slower moves, and in particular the quick attack is very slow - so there is a significant advantage for the moves that charge more quickly.
One thing that's ignored here, by the way, is difficulty to dodge. That's something not taken into account by most calculators; but some charge attacks are much harder to dodge than others - think Body Slam versus Hyper Beam. Any idiot can dodge hyper beam, it's almost hard to dodge because it takes SO long to show up, but Body Slam is much harder as it has a very quick animation. See this thread on Reddit for example.