Steam – Is it possible to disable cloud saves for specific games/apps

The full up-to-date list.

Things to note:

• All Valve games use the Steam cloud.
• The majority of games on that list are indie titles, not AAA games, probably because those titles were written specifically with Steam in mind. Still, there are quite a few AAA games there as well.

As far as I know, you can't do that. If one of you wanted to play single player, then you could possibly set one computer to Offline Mode before starting the game, and then the other person should be able to log in on the other account and play multiplayer, but both of you being online at the same time should not be possible.

Keep in mind, this is technically not allowed. Steam's agreement says you're not allowed to share your account or your games, that includes your fiancee. I don't think they actually do anything about it as long as you're not talking about it on steam chat or their forums. However, you still risk losing your account and all your games when bypassing their rules.

EDIT: As of mid 2014, Steam has released Steam Family Sharing, which enables the sharing of Steam libraries. However, this system does not work on a per-title basis (only during the beta), but rather - If one title is being played, all other titles cannot be played (unless it's the same user that's using the library that is launching the second/whatever-is-after-first program).