The King slime spawns instead of a slime in the outer part of the map, according to the wiki. Does the king slime also have a biome requirement, or does it just need a biome that spawns slimes that can be upgraded?
Terraria – King slime biome requirement
terraria
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Best Answer
Essentially, once you're in the eligible area for the King Slime to spawn, any slime has a chance to spawn as a King Slime.
So you're basically spot on - the only requirements that need to be fulfilled are
The second requirement could technically be interpreted as a "biome requirement" anyway.
Also The King™ needs enough space to spawn, obviously and trivially.