Yes, this spell will control a lich.
Control Undead states:
This spell enables you to control undead creatures for a short period of time. You command them by voice and they understand you, no matter what language you speak. Even if vocal communication is impossible, the controlled undead do not attack you. At the end of the spell, the subjects revert to their normal behavior.
Intelligent undead creatures remember that you controlled them, and they may seek revenge after the spell's effects end.
So "Intelligent undead" can be controlled; however the Lich has several lines of defence against this spell.
- Max 2 HD/Level spell limit. Although admittedly not much of a barrier.
- Will save. The lich is going to have a VERY large bonus for this.
- Spell resistance. And probably this as well.
- Spell Immunity, Greater. Any self-respecting lich will know this spell and have "control undead" as one of the spells it's immune to. Wouldn't you?
Note also, any lich is going to know this spell and have ways around it. The only thing the lich is restricted from (initially) is attacking the caster this isn't going to stop them (until commanded) from...
- Teleporting away.
- Casting silence around themselves so they can't hear you
- Attacking any of your allies.
- Perverting the words of anything you say. "Where is your phylactery?" (The lich answers in Abysmal, which the player doesn't speak.) "Tell me in Common where your phylactery is?" (The lich says "It is under the sacred cloth of my father.") and so on... all buying it time to get away.
- And so on.
It's not a hands-down game winner against a Lich,
I wanted to all an alternative from all the other types of posts I see (which more or less assume this is possible). That being said this is more my interpretation of how the rules are supposed to be viewed.
The rules for how you gain new spells as a wizard are fairly clear - you gain them as you level, based on your spell book. Now that being said, it is my assumption that a Wizard is already using his downtime to learn new spells, update his notes, and in general improve his spells. My example to support this is that a fighter doesn't just go to town, sit down and drink/sleep all night (well fair point, some probably do). But most are probably training, practicing their weapon skills, or improving themselves.
I would say the rules for Wizards also support this...
The spells the you add to your spell book as you gain levels reflect the arcane research you conduct on your own
Since if you are not doing this research in your down time, when are you doing it?
Aside: Now, it would be a separate issue if say the Wizard found a spell book, or notes about some spells he did not already know. But this strikes me as more of the role-playing side, and I don't intend to cover that in my answer.
If you decide to allow it, I would highly recommend making it massively less useful for your Wizard. A good method would be to use the spell copying table mentioned in other answers and use that as the time required (I expect this would dissuade him from trying anything other then the lowest level spells). It seems the rules outlined for this (both time and money) are fairly penalizing - I might also add a failure chance for a bit of home-brew flavor as well (e.g. the Wizard was attempting to write a spell he did not already know and did not gain through practical use).
Best Answer
By RAW, the surest way to become a Lich is to use the occult ritual : Eternal Apotheosis
The main problem is to find a way to learn this ritual.
Depending on your GMs approval, a DC 24 Intelligence check might be enough to learn it from scratch.
If you GM approves, this is the easiest way.
If you GM does not approves, there's a longer but surer path.
Who could teach it without taking your soul or devotion in payment ?
Your surest bet is the Greater True Name Feat (taken at lvl 15)
With this feat, you can learn the true name of a Lilitu Which has just the right number of HD to be called in this manner.
As per the True Name description :
Which means the Lilitu will do everything in her power to help you for free.
Now how can you be sure that the Lilitu knows this Ritual ?
Well. Orcus, the arch demon of undeath and patron of Liches happens to have lots of Lilitu at his service
Also, Lilitu are demons of sin, they will try to push mortals to commit sins by granting them Wishes. And becoming a Lich is typically the kind of "sin" Orcus encourages.
So, use the feat to find the True Name of a Lilitu that worships Orcus and ask her to use her "Wish" ability to explain you the Eternal Apotheosis ritual and threaten to spread her True Name if she doesn't. (or tries to trick you in any way.)
Once the Occult Ritual is learnt, all you have to do is perform the ritual and make your Phylactery.
Beware that the ritual is inherently a heinously evil act and involves a number of DC 34 skill checks. And in case of failure, your character will turn into a forsaken Lich and die in matter of months.
This is the safest path I could find to Lichdom, which doesn't mean that it is safe at all. The Lilitu might try to get revenge on you and purposely give you a false ritual destined to fail or come during the ritual to prevent you from succeeding in it's accomplishment, all of this is at your DMs discretion of course.